Luminescence of Metal Complexes

Nail M. Shavaleev

Shavaleev, N. M.*; Eliseeva, S. V.; Scopelliti, R.; Bunzli, J.-C. G.*

Inorg. Chem. 2015, 54, 9166-9173.

Green phosphorescence and electroluminescence of sulfur pentafluoride-functionalized cationic iridium(III) complexes

Shavaleev, N. M.; Xie, G.; Varghese, S.; Cordes, D. B.; Slawin, A. M. Z.; Momblona, C.; Orti, E.; Bolink, H. J.; Samuel, I. D. W.*; Zysman-Colman, E.*

Inorg. Chem. 2015, 54, 5907-5914.

Synthesis and spectroscopy of anionic tridentate benzimidazole-pyridine carboxylate and tetrazolate chromophore ligands

Shavaleev, N. M.*; Eliseeva, S. V.

Inorg. Chim. Acta 2015, 427, 81-86.

Synthesis, spectroscopy, and electrochemistry of ionic hosts for organic electronics

Shavaleev, N. M.*; Nazeeruddin, Md. K.*

J. Mol. Struct. 2015, 1081, 244-247.

Tridentate benzimidazole-pyridine tetrazolates as sensitizers of europium luminescence

Shavaleev, N. M.*; Eliseeva, S. V.; Scopelliti, R.; Bunzli, J.-C. G.*

Inorg. Chem. 2014, 53, 5171-5178.

Host-guest blue light-emitting electrochemical cells

Pertegas, A.; Shavaleev, N. M.*; Tordera, D.; Orti, E.; Nazeeruddin, Md. K.; Bolink, H. J.*

J. Mater. Chem. C 2014, 2, 1605-1611. Front Cover

Redox properties of cobalt(II) complexes with azole-pyridines

Shavaleev, N. M.*; Kessler, F.; Gratzel, M.; Nazeeruddin, Md. K.*

Inorg. Chim. Acta 2013, 407, 261-268.

Steric hindrance at metal centre quenches green phosphorescence of cationic iridium(III) complexes with 1-(2-pyridyl)-pyrazoles

Shavaleev, N. M.*; Scopelliti, R.; Gratzel, M.; Nazeeruddin, Md. K.*

Inorg. Chim. Acta 2013, 404, 210-214.

Pulsed-current versus constant-voltage light-emitting electrochemical cells with trifluoromethyl-substituted cationic iridium(III) complexes

Shavaleev, N. M.*; Scopelliti, R.; Gratzel, M.; Nazeeruddin, Md. K.*; Pertegas, A.; Roldan-Carmona, C.; Tordera, D.; Bolink, H. J.*

J. Mater. Chem. C 2013, 1, 2241-2248.

Extreme tuning of redox and optical properties of cationic cyclometalated iridium(III) isocyanide complexes

Shavaleev, N. M.*; Monti, F.; Scopelliti, R.; Baschieri, A.; Sambri, L.; Armaroli, N.*; Gratzel, M.; Nazeeruddin, Md. K.*

Organometallics 2013, 32, 460-467.

How to blue-shift phosphorescence color of iridium(III) complexes

Shavaleev, N. M.*; Scopelliti, R.; Gratzel, M.; Nazeeruddin, Md. K.*

Inorg. Chim. Acta 2013, 396, 17-20.

Phosphorescence of iridium(III) complexes with 2-(2-pyridyl)-1,3,4-oxadiazoles

Shavaleev, N. M.*; Scopelliti, R.; Gratzel, M.; Nazeeruddin, Md. K.*

Inorg. Chim. Acta 2013, 394, 295-299.

Blue Phosphorescence of Trifluoromethyl- and Trifluoromethoxy-Substituted Cationic Iridium(III) Isocyanide Complexes

Shavaleev, N. M.*; Monti, F.; Scopelliti, R.; Armaroli, N.*; Gratzel, M.; Nazeeruddin, Md. K.*

Organometallics 2012, 31, 6288-6296.

Efficient orange light-emitting electrochemical cells

Tordera, D.; Pertegas, A.; Shavaleev, N. M.*; Scopelliti, R.; Orti, E.; Bolink, H. J.*; Baranoff, E.; Gratzel, M.; Nazeeruddin, Md. K.*

J. Mater. Chem. 2012, 22, 19264-19268.

Phosphorescent cationic iridium(III) complexes with cyclometalating 1H-indazole and 2H-[1,2,3]-triazole ligands

Shavaleev, N. M.*; Scopelliti, R.; Gratzel, M.; Nazeeruddin, Md. K.*

Inorg. Chim. Acta 2012, 388, 84-87.

Bright Blue Phosphorescence from Cationic Bis-Cyclometalated Iridium(III) Isocyanide Complexes

Shavaleev, N. M.*; Monti, F.; Costa, R.; Scopelliti, R.; Bolink, H. J.; Orti, E.; Accorsi, G.; Armaroli, N.*; Baranoff, E.; Gratzel, M.; Nazeeruddin, Md. K.*

Inorg. Chem. 2012, 51, 2263-2271.

Charged cyclometalated iridium(III) complexes that have large electrochemical gap

Shavaleev, N. M.*; Scopelliti, R.; Baranoff, E.; Gratzel, M.; Nazeeruddin, Md. K.*

Inorg. Chim. Acta 2012, 383, 316-319. PDF + SI

N-Aryl Chromophore Ligands for Bright Europium Luminescence

Shavaleev, N. M.; Eliseeva, S. V.; Scopelliti, R.; Bunzli, J.-C. G.*

Inorg. Chem. 2010, 49, 3927-3936. PDF + SI

Designing Simple Tridentate Ligands for Highly Luminescent Europium Complexes

Shavaleev, N. M.; Eliseeva, S. V.; Scopelliti, R.; Bunzli, J.-C. G.*

Chem. Eur. J. 2009, 15, 10790-10802. VIPaper PDF + SI

Surprisingly Bright Near-Infrared Luminescence and Short Radiative Lifetimes of Ytterbium in Hetero-Binuclear Yb-Na Chelates

Shavaleev, N. M.; Scopelliti, R.; Gumy, F.; Bunzli, J.-C. G.*

Inorg. Chem. 2009, 48, 7937-7946. PDF + SI

Highly Luminescent Homoleptic Europium Chelates

Shavaleev, N. M.; Gumy, F.; Scopelliti, R.; Bunzli, J.-C. G.*

Inorg. Chem. 2009, 48, 5611-5613. PDF + SI

Benzothiazole- and Benzoxazole-Substituted Pyridine-2-Carboxylates as Efficient Sensitizers of Europium Luminescence

Shavaleev, N. M.; Scopelliti, R.; Gumy, F.; Bunzli, J.-C. G.*

Inorg. Chem. 2009, 48, 6178-6191. PDF + SI

Modulating the Near-Infrared Luminescence of Neodymium and Ytterbium Complexes with Tridentate Ligands Based on Benzoxazole-Substituted 8-Hydroxyquinolines

Shavaleev, N. M.; Scopelliti, R.; Gumy, F.; Bunzli, J.-C. G.*

Inorg. Chem. 2009, 48, 2908-2918. PDF + SI

Near-Infrared Luminescence of Nine-Coordinate Neodymium Complexes with Benzimidazole-Substituted 8-Hydroxyquinolines

Shavaleev, N. M.; Scopelliti, R.; Gumy, F.; Bunzli, J.-C. G.*

Inorg. Chem. 2008, 47, 9055-9068. PDF + SI

Platinum(II) Diimine Complexes with Catecholate Ligands Bearing Imide Electron-Acceptor Groups: Synthesis, Crystal Structures, (Spectro)Electrochemical and EPR studies, and Electronic Structure

Shavaleev, N. M.; Davies, E. S.; Adams, H.; Best, J.; Weinstein, J. A.*

Inorg. Chem. 2008, 47, 1532-1547. PDF + SI

Visible-Light Excitation of Infrared Lanthanide Luminescence via Intra-Ligand Charge-Transfer State in 1,3-Diketonates Containing Push-Pull Chromophores

Shavaleev, N. M.; Scopelliti, R.; Gumy, F.; Bunzli, J.-C. G.*

Eur. J. Inorg. Chem. 2008, 1523-1529. PDF + SI

Sensitised near-infrared luminescence from lanthanide(III) centres using Re(I) and Pt(II) diimine complexes as energy donors in d-f dinuclear complexes based on 2,3-bis(2-pyridyl)pyrazine

Kennedy, F.; Shavaleev, N. M.; Koullourou, T.; Bell, Z. R.; Jeffery, J. C.; Faulkner, S.*; Ward, M. D.*

Dalton Trans. 2007, 1492-1499. PDF

Platinum(II) imidazo[4,5-f]-1,10-phenanthroline chloride and thiolate complexes: Synthesis and crystal structures

Shavaleev, N. M.; Adams, H.; Weinstein, J. A.*

Inorg. Chim. Acta 2007, 360, 700-704. PDF + SI

Platinum(II) phosphine complexes with acetylene ligands containing 1,4,5,8-naphthalenediimide: synthesis, crystal structure and electrochemistry

Shavaleev, N. M.; Adams, H.; Best, J.; Weinstein, J. A.*

J. Organomet. Chem. 2007, 692, 921-925. PDF + SI

Deep-Red Luminescence and Efficient Singlet Oxygen Generation by Cyclometalated Platinum(II) Complexes with 8-Hydroxyquinolines and Quinoline-8-thiol

Shavaleev, N. M.; Adams, H.; Best, J.; Edge, R.; Navaratnam, S.; Weinstein, J. A.*

Inorg. Chem. 2006, 45, 9410-9415. PDF + SI

Syntheses and Crystal Structures of Dinuclear Complexes Containing d-Block and f-Block Luminophores. Sensitization of NIR Luminescence from Yb(III), Nd(III), and Er(III) Centers by Energy Transfer from Re(I)- and Pt(II)-Bipyrimidine Metal Centers

Shavaleev, N. M.; Accorsi, G.; Virgili, D.; Bell, Z. R.; Lazarides, T.; Calogero, G.; Armaroli, N.*; Ward, M. D.*

Inorg. Chem. 2005, 44, 61-72. PDF

Complexes of substituted derivatives of 2-(2-pyridyl)benzimidazole with Re(I), Ru(II) and Pt(II): structures, redox and luminescence properties

Shavaleev, N. M.; Bell, Z. R.; Easun, T. L.; Rutkaite, R.; Swanson, L.; Ward, M. D.*

Dalton Trans. 2004, 3678-3688. PDF + Additions and Corrections

New ligands in the 2,2'-dipyridylamine series and their Re(I) complexes; synthesis, structures and luminescence properties

Shavaleev, N. M.; Barbieri, A.; Bell, Z. R.; Ward, M. D.*; Barigelletti, F.*

New. J. Chem. 2004, 28, 398-405. PDF

Sensitized Near-Infrared Emission from Complexes of Yb(III), Nd(III) and Er(III) by Energy-Transfer from Covalently Attached Pt(II)-Based Antenna Units

Shavaleev, N. M.; Moorcraft, L. P.; Pope, S. J. A.; Bell, Z. R.; Faulkner, S.*; Ward, M. D.*

Chem. Eur. J. 2003, 9, 5283-5291. PDF

Sensitised near-infrared emission from lanthanides using a covalently-attached Pt(II) fragment as an antenna group

Shavaleev, N. M.; Moorcraft, L. P.; Pope, S. J. A.; Bell, Z. R.; Faulkner, S.*; Ward, M. D.*

Chem. Commun. 2003, 1134-1135. RSC Hot Article PDF

Syntheses and structures of mononuclear {Re(CO)3Cl(NN)} 'complex ligands' with a pendant imino-pyridine binding site, and preparation of some heterodinuclear Re(I)-lanthanide(III) complexes

Shavaleev, N. M.; Bell, Z. R.; Accorsi, G.; Ward, M. D.*

Inorg. Chim. Acta 2003, 351, 159-166. PDF

Visible-light sensitisation of near-infrared luminescence from Yb(III), Nd(III) and Er(III) complexes of 3,6-bis(2-pyridyl)tetrazine

Shavaleev, N. M.; Pope, S. J. A.; Bell, Z. R.; Faulkner, S.*; Ward, M. D.*

Dalton Trans. 2003, 808-814. PDF

A simple, general synthesis of mixed d–f complexes containing both {Re(CO)3Cl(diimine)} and lanthanide-tris(beta-diketonate) luminophores linked by bis-diimine bridging ligands

Shavaleev, N. M.; Bell, Z. R.; Ward, M. D.*

J. Chem. Soc., Dalton Trans. 2002, 3925-3927. PDF

Water enhances quantum yield and lifetime of luminescence of europium(III) tris-beta-diketonates in concentrated toluene and acetonitrile solutions

Voloshin, A. I.*; Shavaleev, N. M.; Kazakov, V. P.

J. Lumin. 2001, 93, 191-197. PDF

Luminescence of Praseodymium(III) chelates from two excited states (3P0 and 1D2) and its dependence on ligand triplet state energy

Voloshin, A. I.*; Shavaleev, N. M.; Kazakov, V. P.

J. Lumin. 2001, 93, 199-204. PDF

Mono-thio-beta-diketones - a new type of ligands suitable for sensitization of lanthanide luminescence. Infrared luminescence of an intensely colored neodymium and ytterbium mono-thio-beta-diketonate chelates

Voloshin, A. I.*; Shavaleev, N. M.; Kazakov, V. P.

J. Lumin. 2001, 93, 115-118. PDF

Water enhances photoluminescence intensity of europium(III), terbium(III) and samarium(III) tris-beta-diketonates in toluene solutions and chemiluminescence intensity of europium(III) and samarium(III) tris-beta-diketonates in the reaction with dioxetane

Voloshin, A. I.*; Shavaleev, N. M.; Kazakov, V. P.

J. Photochem. Photobiol. A: Chem. 2000, 136, 203-208. PDF

Chemiluminescence of praseodymium(III), neodymium(III) and ytterbium(III) beta-diketonates in solution excited from 1,2-dioxetane decomposition and singlet-singlet energy transfer from ketone to rare-earth beta-diketonates

Voloshin. A. I.*; Shavaleev, N. M.; Kazakov, V. P.

J. Lumin. 2000, 91, 49-58. PDF

Water enhances the luminescence intensity of beta-diketonates of trivalent samarium and terbium in toluene solutions

Voloshin. A. I.*; Shavaleev, N. M.; Kazakov, V. P.

J. Photochem. Photobiol. A: Chem. 2000, 134, 111-117. PDF

Singlet-singlet energy transfer from ketone to lanthanide ion beta-diketonates as studied by chemiluminescence quenching. First observation of infrared chemiluminescence of neodymium(III) and ytterbium(III) in solution

Voloshin, A. I.*; Shavaleev, N. M.; Kazakov, V. P.

J. Photochem. Photobiol. A: Chem. 2000, 131, 61-65. PDF

Chemiluminescence in visible and infrared spectral regions and quantum chain reactions upon thermal and photochemical decomposition of adamantylideneadamantane-1,2-dioxetane in the presence of chelates Pr(DPM)3 and Pr(FOD)3

Kazakov, V. P.*; Voloshin, A. I.; Shavaleev, N. M.

J. Photochem. Photobiol. A: Chem. 1998, 119, 177-186. PDF

Chemiluminescence of Pr3+ in the visible region from the 3P1, 3P0, 1D2 levels upon decomposition of adamantylideneadamantane-1,2-dioxetane catalysed by beta-diketonates Pr(FOD)3 and Pr(DPM)3. An unusual route for activator chemiexcitation

Kazakov, V. P.*; Voloshin, A. I.; Shavaleev, N. M.

Mendeleev Commun. 1998, 8, 110-112. PDF

The anomalous influence of water on the intensity and lifetime of fluorescence in tris(benzoyltrifluoroacetonate)europium(III)

Kazakov, V. P.*; Voloshin, A. I.; Ostakhov, S. S.; Shavaleev, N. M.

Mendeleev Commun. 1998, 8, 47-49. PDF

The influence of excitation of the 4f-orbital of Eu(fod)3 on complex formation with adamantanone and anomalous enhancement of Eu3+ luminescence under the action of H2O and D2O molecules in toluene

Ostakhov, S. S.; Voloshin, A. I.; Kazakov, V. P.*; Shavaleev, N. M.

Russ. Chem. Bull. 1998, 47, 1466-1471. PDF

Professional Experience

Research Fellow, 04.2014-03.2015

Dr. Eli Zysman-Colman

Prof. Ifor D. W. Samuel

Schools of Chemistry and Physics & Astronomy, University of St Andrews

Scientist, 02.2010-03.2013

CELLO Project

Prof. Mohammad Khaja Nazeeruddin

Prof. Michael Gratzel

Laboratory of Photonics and Interfaces (LPI), ISIC, Ecole Polytechnique Federale de Lausanne (EPFL)

Scientist, 05.2007-01.2010

Prof. Jean-Claude G. Bunzli

Laboratory of Lanthanides Supramolecular Chemistry (LCSL), ISIC, Ecole Polytechnique Federale de Lausanne (EPFL)

Research Assistant

Prof. Julia A. Weinstein

02.2005-03.2007, Department of Chemistry, University of Sheffield

12.2004-01.2005, School of Chemistry, University of Nottingham

Research Scholar, 09.2003-08.2004

Prof. Kenneth N. Raymond

College of Chemistry, University of California at Berkeley

Research Assistant, 02.2003-06.2003

Royal Society of Chemistry/NATO Postdoctoral Fellowship, 02.2002-01.2003

Prof. Michael D. Ward

School of Chemistry, University of Bristol

Staff Scientist, 02.2001-01.2002, info

Dr. Viktor V. Ragulin

Ufa Branch of the Yugansk Oil Research and Development Project Institute YuganskNIPIneft, Oil Company YUKOS (now part of ROSNEFT)

Engineer, 08.1997-11.1997

Prof. Alexander I. Voloshin

Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences

Education

Ph.D. Physical Chemistry, 11.1997-12.2000, info

Prof. Alexander I. Voloshin

Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences

M.Sc. Chemistry (with honours), 09.1992-07.1997

Bashkir State University

09.1982-06.1992

School 39, Ufa

Awards

Royal Society of Chemistry/NATO

Postdoctoral Fellowship 2001 (NATO/01A/CC)

International Soros Science Education Program

Postgraduate Student 1999 (a99-408) and 2000

Student 1995 (s857) and 1997 (s97-62)